Abstract

We studied the effect of surface modification and particle size on the oxidation and corrosion behavior of neodymium–iron–boron (Nd–Fe–B) magnetic alloy powders by using thermal analysis to accelerate efforts to develop useful poly(phenylene sulfide) bonded Nd–Fe–B magnets. The results indicate that coating the Nd–Fe–B powders with a coupling agent provides the required oxidation and corrosion resistance for the targeted processing conditions. The coated rare earth powders are thermally and environmentally stable at elevated temperatures and in a 100% humid environment, where commercial rare earth alloy magnets are not usable. The coating treatment more significantly affects the small particle powders. A mechanism accounting for the improved thermal and environmental stability is presented and discussed. Magnetic measurements were performed to verify the thermal analysis results.

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