Polymer-Based White-Light-Emitting Electrochemical Cells with Very High Color-Rendering Index Based on Blue-Green Fluorescent Polyfluorenes and Red-Phosphorescent Iridium Complexes.

Abstract

Application of the concept of three-color (red (R), green (G), and blue (B)) light-mixing to obtain white light is the most suitable way to realize white-light-emitting devices with very high color-rendering indices (CRI). White-light-emitting devices based on the three-color-mixing method could be used to create lighting and display technologies. Here, white-light-emitting electrochemical cells (LECs) with very high CRIs are reported, which were fabricated by using blend films composed of a fluorescent π-conjugated polymer (FCP), poly(9,9-dioctylfluorene-co-benzothiadiazole) (PFBT), and a phosphorescent iridium complex, [Ir(ppy)2 (biq)]+ (PF6 )- (where (ppy)- =2-phenylpyridinate and biq=2,2'-biquinoline). The LECs fabricated with PFBT, the benzothiadiazole content of which is 0.01 mol %, showed blue electroluminescence (EL) emission originating from the fluorene segments and green EL emission from the benzothiadiazole units simultaneously. White LECs were then realized by adding red-emitting Ir complexes as guest molecules to the blue-green-emitting PFBT. By optimizing the proportions of the PFBT and Ir complexes in the active layers (PFBT/[Ir(ppy)2 (biq)]+ (PF6 )- =1:0.2 (mass ratio)), white-light emission with Commission Internationale de l'Eclairage (CIE) coordinates of (0.29, 0.34) and a very high CRI value of 91.5 was achieved through RGB color-mixing. It was noted that the emission mechanism was based on Förster resonance energy transfer and Dexter energy transfer from excited PFBT to [Ir(ppy)2 (biq)]+ (PF6 )- . The utilization of LECs based on blue-green FCPs and red Ir complexes looks very promising for the prospect of realizing white-light-emitting devices with very high CRIs.