Polymer dispersed cholesteric liquid crystals with combined photo- and mechanochromic response

Abstract

The development of stimuli-sensitive systems is one of the newest and most promising directions in the field of modern materials science. The combination of various types of sensitivity in the same material opens the possibility of creating complex devices with a wide range of potential applications. This work deals with the design and preparation of new composite materials based on plasticized polyvinyl alcohol (PVA) films containing droplets of cholesteric liquid crystals (CLC). Mechanical stretching of elastic composite films results in a change in optical properties, namely selective light reflection (SLR), from CLC droplets. This in turn transforms the structure and optical properties of the entire polymer matrix. Such a process represents a certain mechano-optic response of the polymer matrix to the influence of mechanical deformation. The introduction of a chiral photochromic dopant into a composite film makes it possible to transform such a film into a photochromic material with the ability to control its optical properties using, for example, UV irradiation. Therefore, mechanical deformation of a polymer composite leads to a change in its optical properties (SLR) caused by a change chiral supramolecular structure of cholesteric mesophase. At the same time, UV irradiation of a polymer film induces E-Z isomerization process in the chiral photochromic dopant, altering its molecular shape and helical twisting power. This enables the using of this process for remote and contactless control of the composite optical properties. In addition, this feature allows one to implement the photopatterning and the recording of a latent image, which appears under the influence of a mechanical field.