Abstract
Ultraviolet-ozone (UV-O3) treatment of polyarylene, a semiconductor dielectric polymer, has been characterized using contact angle measurements, x-ray photoelectron spectroscopy, spectroscopic ellipsometry (SE), and ellipsometric porosimetry. Significant modification of the film surface composition is already observed after a short exposure time (30s). Longer treatment time leads to further increase in oxygen concentration and formation of an oxidized surface layer and densification of the film as evidenced by solvent adsorption data. Results obtained from SE indicate few changes in optical parameters, thickness, and refractive index (RI) of the film, up to 5min of UV-O3 treatment. Increasing the exposure time further leads to a substantial change in film thickness and an increase in RI. The same trend was observed for porous polyarylene but to a stronger extent. A dense layer at the porous polymer surface is only formed after 20min of treatment. Under these conditions, the optical properties of the material are strongly modified, with a substantial thickness shrinkage and increase in RI.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
