Polymer composite membranes as SERS substrate materials: Recyclable and highly stable

Abstract

Surface-enhanced Raman spectroscopy (SERS), as an emerging molecular-level detection technology, has attracted considerable research attention, especially in the context of substrate materials exhibiting Raman enhancement effects. Membrane materials, owing to their commendable uniformity, stability, and ease of modification, hold a pivotal position in the landscape of SERS substrate materials. However, existing SERS substrates based on membrane materials have limited adaptability to a spectrum of extreme environments, including but not limited to high or low pH, elevated salinity, and corrosive solutions. Additionally, SERS substrate materials are synonymous with “waste” and “high investment” because of their inherent disposable nature. This study introduces a pioneering approach, presenting a polymer composite membrane founded on epoxy resin, cellulose paper, and nanometal particles as a novel SERS substrate material. Given the outstanding stability of epoxy resin, the substrate material exhibits normal functionality in environments ranging from −80 ℃ to 100 ℃, with pH levels spanning 1 to 13, and in highly acidic solutions (concentration ≤3 %) and highly alkaline solutions (concentration ≤0.1 M). Moreover, the cleanability inherent in the polymer composite membrane renders the substrate material recyclable. Experimental findings reveal that even after six repeated uses, the substrate material sustains a stable Raman signal enhancement effect. The integration of recyclability and heightened stability makes this SERS substrate material a promising candidate for real-time monitoring and batch testing in chemical production processes or other complex environments.