Abstract

Low density polyethylenes made by the known high pressure processes show significantly different molecular structures. The physical and technological properties are closely related to molecular structure and morphology. For example, the adhesive strength of a laminate consisting of an ozone treated low density polyethylene film and an aluminum foil depends strongly on the synthesis conditions. The molecular structures and dilute solution properties of many fully aromatic thermotropic liquid crystalline copolyesters can now be determined using the new solvent 3,5-bis(trifluoromethyl)phenol. A typical random copolyester was fractionated by precipitation from solution, and the fractions were studied in detail by viscometry, integrated and dynamic light scattering, and size exclusion chromatography. From the structure data thus obtained the molecular mass distribution and the persistence length were calculated. Polymer blends, block copolymers, and graft copolymers can be characterized by fractionation procedures using demixing solvents in an ultracentrifuge and subsequent analysis of the fractions.

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