Polylactide single-polymer composites with a wide melt-processing window based on core-sheath PLA fibers

Abstract

Polylactide (PLA) single polymer composites (SPCs) were prepared using PLA nonwovens made of core-sheath PLA fibers as raw materials by hot-pressing. The core and sheath materials were poly(l-lactide) (PLLA) and PLA with d-lactide of about 10mol% (PLA90), respectively. The melt processing window of PLA SPCs reached more than 40°C. The effects of hot-pressing temperature on the crystallinity, the size distribution of crystallites, the lamellar thickness and mechanical property of PLA SPCs were significant while those of hot-pressing pressure were small. The strong interfacial adhesion between matrix and reinforcement led to high mechanical properties of PLA SPCs. For pure PLA materials prepared at 180°C, the tensile strength (σb), elongation at break (εb), the work of rupture (W) and impact strength (αcU) were only 19MPa, 1.8%, 0.15J, and 2.8kJ/m2, respectively while those of the SPCs prepared at 130–160°C were 47–65MPa, 15–32%, 9–22J, and 14.9–67.2kJ/m2, respectively. With the increase of hot-pressing temperature, the σb, W and αcU decreased.