Poly(lactic acid)-Poly(butylene succinate)-Sugar Beet Pulp Composites; Part II: Water Absorption Characteristics with Fine and Coarse Sugar Beet Pulp Particles; A Phenomenological Investigation.

Abstract

Sugar beet pulp (SBP) is a residue available in large quantities from the sugar industry, and can serve as a cost-effective bio-based and biodegradable filler for fully bio-based compounds containing bio-based polyesters. The composition of SBP is characterized by an unusually high content of pectins, which are known as water-binding substances. Their molecular structure and the poor gelling properties, compared to other pectin sources, do not allow industrial use on a larger scale. However, good water absorption capacity can be advantageous for promoting plastics degradation or disintegration in the environment. In this study, we evaluated the water absorption capacity and processes of SBP-filled composites with bio-based polyesters on a longer time scale. We analyzed water absorption from a phenomenological point of view and tried to derive basic parameters for the general description of the composites behavior. We found that polar polyesters or polyester blends filled with higher amounts of especially coarse SBP suffer disintegration within a few weeks when supplied with sufficient water. On the other hand, less polar polyesters filled with fine SBP rather absorb water but do not show disintegration for several months. On a time scale of a few years, catalytic disintegration of the composites appears to be independent of the addition of SBP.