Polylactic acid/Gemini surfactant modified clay bio-nanocomposites: Morphological, thermal, mechanical and barrier properties

Abstract

To improve PLA's properties and overcome its drawbacks such us poor thermal stability, resistance and gas barrier properties, several studies have been performed using different nanofillers. In this work, PLA nanocomposites reinforced by three organoclays, OMt(8-4-8), OMt(10-4-10) and OMt(12-4-12) at various weight percentages (1 and 3 wt%) were prepared by melt mixing using a twin-screw extruder. The organoclays were obtained from sodium montmorillionite and gemini surfactants bearing different hydrophobic chain lengths. The resulting nanocomposites have been characterized in terms of composition and morphology by X-ray diffraction analysis (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The thermal stability and cold crystallization behavior were accessed by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The effect of clay composition and concentration on the mechanical and rheological properties of the nanocomposites as well as their water vapor permeability has been also investigated. The resulting nanocomposites exhibit a significantly reduced permeability as compared to unfilled PLA and an improved young modulus and toughness at the detriment of ductility.