Abstract
Polyynes, 8. ‐ Synthesis of Amino and Bisamino Derivatives of OctatetrayneThe (7,8,8‐trichloro‐7‐octene‐1,3,5‐triynyl)amines 4a,b, formed by the reaction of the corresponding lithium 4‐aminobutadiynides 3 with perchlorobutenyne 1, are dechlorinated by butyllithium to give the lithium 8‐aminooctatetraynides 5a,b. The latter react with chloromethyldiphenylsilane or with cyclohexanone to give the silylated and hydroxyalkylated compounds 6a,b and 7b, respectively. The unsymmetrically substituted octatetraynediamines 9a,b are obtained by treatment of the lithium compounds 5 with cyanogen bromide and by treatment of the formed bromoacetylenes 8 with piperidine or morpholine.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
