Abstract
Decafluorocyclohepta-1,4-diene and fuming sulphuric acid at 100° gave a bright yellow solution which was decolourised on dilution with water to give 2H,4H-hexafluoro-1,5-dihydroxy-8-oxabicyclo(3,2,1)octan-3-one. This was methylated with diazomethane in ether to give 2H,4H-hexafluoro-1,5-dimethoxy-8-oxabicyclo(3,2,1)octan-3-one and 2H-hexafluoro-1,3,5-trimethoxy-8-oxabicyclo(3,2,1)oct-3-ene. The crystal and molecular structure of the former compound was determined by a single crystal X-ray analysis from three-dimensional counter data.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
