Polyethylene ceramic separators with semi-interpenetrating polymer network boosting fast-charging cycle capacity retention and safety for lithium-ion batteries

Abstract

Fast-charging lithium-ion batteries (LIBs) have recently received significant attention. In current commercial LIBs, lithium precipitation frequently occurs under long-term cycling and fast-charging conditions, adversely affecting their cycle capacity retention and safety. The primary cause of lithium precipitation is electrolyte loss during long-term cycling. In this study, a thermoplastic polyurethane/polyurethane acrylate semi-interpenetrating polymer network ceramic separator with high electrolyte retention (200%) and interfacial adhesion (6.6 N) is prepared and without a decrease in the energy density. The LiNi0.8Mn0.1Co0.1O2/graphite batteries fabricated with this separator show excellent electrochemistry properties (300 cycles, 1.5 C, discharge capacity of 3677 mAh, capacity retention of 93%). Furthermore, this study presents a novel strategy to mitigate the issue of lithium precipitation in fast-charging LIBs. Therefore, this functional separator is a promising alternative for the conventional commercial polyvinylidene difluoride separators and provides a new avenue for developing the next generation of fast-charging devices.