Abstract
Abstract Studies on the reactions of oxiranes with various carbonates (cyclic and linear, aliphatic and aromatic) in the presence of BF3·Et2O are presented. The reaction mechanism is proposed. It was found that poly(ether-carbonate) is formed not only as the product of polymerization of spiroorthocarbonate but mainly directly from oxirane and cyclic carbonate. Spiroorthocarbonate is one of the possible reaction products of trioxocarbenium ion - the product of its cyclization. It was shown that as a result of the copolymerization of epichlorohydrin with ethylene carbonate initiated by BF3·Et20 poly(ether-carbonate) containing of about 10% of units originated from ethylene carbonate and 4-chloromethyl-1,3-dioxolan-2-one was obtained.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
