Abstract
Polyester nanofiltration membranes highlight beneficial chlorine resistance, but their loose structures and negative charge result in poor cations retention precluding advanced use in cations separation. This work designs a new monomer (TET) containing "hydroxyl-ammonium" entities that confer dense structures and positive charge to polyester nanofiltration membranes. The TET monomer undergoes efficient interfacial polymerization with the trimesoyl chloride (TMC) monomer, and the resultant TET-TMC membranes feature one of the lowest molecular weight cut-offs (389Da) and the highest zeta potential (4mv, pH: 7) among all polyester nanofiltration membranes. The MgCl2 rejection of the TET-TMC membrane is 95.5%, significantly higher than state-of-the-art polyester nanofiltration membranes (<50%). The Li+ /Mg2+ separation performance of TET-TMC membrane is on par with cutting-edge polyamide membranes, while additionally, the membrane is stable against NaClO though polyamide membranes readily degrade. Thus the TET-TMC is the first polyester nanofiltration membrane for efficient cations separation.
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