Polyepichlorohydrin grafted poly(phenylene oxide) to construct hydrophilic and hydrophobic microphase separation anion exchange membrane

Abstract

An anion exchange membrane (QAPECH-g-PPO) with polyepichlorohydrin (PECH) as the main chain and poly(phenylene oxide) (PPO) as the side chain was prepared by Williamson etherification reaction. Atomic force microscopy (AFM) and small angle X-ray scattering (SAXS) characterization indicate that PECH grafted with PPO can effectively form a hydrophilic and hydrophobic phase separation structure. The amount of and molecular weight of PPO grafted has different effects on the membrane properties. As the amount of PPO grafted increases, the tensile strength of the membrane gradually increases. When the amount of PPO grafted exceeds 44%, the excessive hydrophobic phase prevents the formation of continuous ionic channels in the hydrophilic phase, leading to a significant decrease in ionic conductivity. When the amount of PPO is 38%, the ionic conductivity can reach 72 mS cm−1 (80 °C), while the swelling ratio is only 15%. Moreover, higher molecular weight PPO at 38% amount improves tensile strength of QAPECH-g-PPO membrane. The higher the molecular weight of PPO, the more stable the π - π stacking structure is formed, leading to more aggregation of hydrophobic phases in the anion exchange membrane and weakened constraints on ion clusters. Therefore, the water absorption and ion conductivity slightly increase.