Abstract
1. New diphenylphosphinylmethyl substituted arenes, derivatives of benzene, naphthalene, and dibenzo-18-crown-6 have been synthesized. 2. The extraction properties of these ligands having limited conformational mobility have been studied relative to tervalent transplutonium elements, europium, and sexivalent uranium. 3. It has been shown that the extraction selectivity is dependent on the relative position of the coordination centers in the aromatic nucleus.
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