Abstract
In the title complex, {[Cu(C8F4O4)(C4H8O2)(H2O)2]·2C4H8O2·2H2O}n, the CuII ion is six-coordinated by two oxygen donors from two trans 2,3,5,6-tetrafluoro-1,4-dicarboxylate (BDC-F4) ligands, two O atoms from two chair 1,4-dioxane ligands and two O atoms from two terminal water molecules, adopting a distorted octahedral coordinated geometry. Each BDC-F4 anion bridges two CuII ions in a bis-monodentate fashion, forming a [Cu(BDC-F4)]n chain. These chains are further linked by bridging 1,4-dioxane ligands, generating a two-dimensional net with approximately rectangular grids of 11.253 × 7.654 Å. Such adjacent parallel layers are connected by O—H⋯O hydrogen bonds between guest water molecules and the uncoordinated carboxylate O atoms and coordinated water molecules into the final three-dimensional supramolecular network.
Highlights
1,4-dioxane ligands and two O atoms from two terminal water molecules, adopting a distorted octahedral coordinated geometry
Each BDC-F4 anion bridges two CuII ions in a bis-monodentate fashion, forming a [Cu(BDC-F4)]n chain. These chains are further linked by bridging 1,4-dioxane ligands, generating a two-dimensional net with approximately rectangular grids of 11.253 7.654 Å
Such adjacent parallel layers are connected by O—H O hydrogen bonds between guest water molecules and the uncoordinated carboxylate O
Summary
1,4-dioxane ligands and two O atoms from two terminal water molecules, adopting a distorted octahedral coordinated geometry. Each BDC-F4 anion bridges two CuII ions in a bis-monodentate fashion, forming a [Cu(BDC-F4)]n chain. These chains are further linked by bridging 1,4-dioxane ligands, generating a two-dimensional net with approximately rectangular grids of 11.253 7.654 Å. Such adjacent parallel layers are connected by O—H O hydrogen bonds between guest water molecules and the uncoordinated carboxylate O atoms and coordinated water molecules into the final threedimensional supramolecular network
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
