Abstract
In the polymeric title complex, [Pb2(CH3CO2)2(C10H6O6S2)]n, the acetate anion functions in a chelating mode and both O atoms also coordinate to adjacent PbII atoms. The naphthalene-1,5-disulfonate dianion, which lies on a center of inversion, is connected to four PbII atoms. The bridging modes of the monoanion and dianion give rise to a three-dimensional coordination polymer. The PbII atom is eight-coordinate in the form of an undefined coordination polyhedron.
Highlights
In the polymeric title complex, [Pb2(CH3CO2)2(C10H6O6S2)]n, the acetate anion functions in a chelating mode and both O atoms coordinate to adjacent PbII atoms
The naphthalene-1,5-disulfonate dianion, which lies on a center of inversion, is connected to four PbII atoms
The PbII atom is eightcoordinate in the form of an undefined coordination polyhedron
Summary
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, People’s Republic of China, bDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia, and cChemistry. Department, Faculty of Science, King Abdulaziz University, PO Box 80203 Jeddah, Saudi Arabia. R factor = 0.030; wR factor = 0.076; data-to-parameter ratio = 15.8. In the polymeric title complex, [Pb2(CH3CO2)2(C10H6O6S2)]n, the acetate anion functions in a chelating mode and both O atoms coordinate to adjacent PbII atoms. The naphthalene-1,5-disulfonate dianion, which lies on a center of inversion, is connected to four PbII atoms. The bridging modes of the monoanion and dianion give rise to a threedimensional coordination polymer. The PbII atom is eightcoordinate in the form of an undefined coordination polyhedron
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