Polycyclic aromatic hydrocarbons in urban and industrial soils of Kerman, the largest city in southeast of Iran: status, source apportionment, ecotoxicology, and health risk assessment

Abstract

ABSTRACT In this study, pollution level, distribution, toxicity, molecular composition, probable sources as well as health risks of polycyclic aromatic hydrocarbons (PAHs) in urban and industrial soils of Kerman metropolis were investigated. Kerman is a fast-growing city and a fine example of an arid city in a developing country. For this purpose, concentrations of 16 individual PAHs in 30 samples taken from the city soils and its industrial zones were determined by gas chromatography/mass spectrometry. The ∑PAHs concentration in urban soil samples varied from 26.1 to 902.8 μg/kg, with the mean and median of 302.6 and 148.4 µg/kg, respectively. In comparison, ∑PAHs in industrial soils ranged from 26.8to 251.9 μg/kg, with the mean and median values of 65.9 and 42.9 µg/kg, respectively. Four-ring PAHs comprise the dominant compounds in urban soils, whereas, two- and three-ring PAHs proved to be the most abundant compounds in industrial soils. Source apportionment was conducted using ring classification, diagnostic ratios, PCA, and multilinear regression (MLR). Also, human health risk assessment was undertaken through employing US EPA standard statistical models. This survey revealed that PAH pollution in urban soils originates mainly from fossil fuel combustion and in industrial soils from petrogenic sources. On the whole, in the Kerman environment, the shares of petroleum combustion, natural gas combustion, and petrogenic sources were 45.32%, 34%, and 20.68% respectively. Based on this study, the ecological risk of PAHs was low-to-moderate, and incremental lifetime cancer risk for children and adults were 1.35 × 10−4 and 1.04 × 10−4 respectively, indicating rather high risks.