Polycyclic Aromatic Hydrocarbons in the Snow Cover in the City of Tyumen (Western Siberia, Russia).

Abstract

Some of Russia's large industrial cities are sources of hazardous contamination in the environment. Tyumen is one of the most rapidly developing cities in Siberia due to oil and gas extraction in the northern Tyumen Region. Concentrations of 14 polycyclic aromatic hydrocarbons (PAH)s deposited with the particulate matter (PM) of snow in the city of Tyumen were determined by liquid chromatography. In the background area, the rate of atmospheric particulate deposition was shown to be low, and the mean total content of 14 PAHs had a value of 6.2 ng L-1, which is lower than many unpolluted areas on Earth. In the city of Tyumen, the mean content of PM was five times higher and the mean total content of 14 PAHs was twenty times higher as compared to the background. The contents of chrysene, benzo(k)fluoranthene, and benzo(a)pyrene were increased by multiples of 78, 77, and 32, respectively. The rates of ∑14 PAH deposition with airborne PM over the winter ranged from 1.1 to 65.5 μg m-2. Calculations of BaP toxic equivalent showed maximal toxicity within the transport zone. Both analysis of spatial distribution and diagnostic ratios showed that the PAHs were mainly from coal combustion and vehicle emissions.