Abstract
The title compound, {(CH3CH2ONH3)2[CdCl4]} n , consists of bilayers of organic CH3CH2ONH3 + cations and infinite [CdCl4] n 2n− inorganic layers. It can be described as an organic–inorganic hybrid layered perovskite. In the crystal structure, the CdII cation is situated at an inversion center and is coordinated by six chloride ions, forming a slightly distorted octahedral coordination polyhedron. By corner-sharing of the [CdCl6] octahedra, infinite [CdCl4] n 2n− inorganic layers are formed, extending parallel to (100). The inorganic layers alternate with bilayers of CH3CH2ONH3 + cations, whereby the connection of the cationic and anionic layers is achieved through N—H...Cl hydrogen bonds and Coulombic interactions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
