Abstract

In the crystal structure of the title compound, [Ni2(NCS)4(C4H4N2)3(CH3OH)2]n, each nickel(II) cation is coordinated by three N-bonded pyrimidine ligands, two N-bonded thio­cyanate anions and one O-bonded methanol mol­ecule in a distorted octa­hedral environment. The asymmetric unit consists of one nickel cation, two thio­cyanate anions and one methanol mol­ecule in general positions, as well as one pyrimidine ligand located around a twofold rotation axis. The crystal structure consists of μ-N:N′ pyrimidine-bridged zigzag-like nickel thio­cyanate chains; these are further linked by μ-N:N-bridging pyrimidine ligands into layers which are stacked perpendicular to the b axis. The layers are connected via weak O—H⋯S hydrogen bonding.

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