Abstract
The title copper(I) polymeric compound, {[Cu(C10H8N2)2]ClO4·0.24H2O}n, obtained by the reaction of Cu(ClO4)2 and 4,4′-bipyridine (4,4′-bpy) under hydrothermal conditions, features a fourfold-interpenetrated diamondoid coordination framework. The asymmetric unit consists of two CuI atoms, three 4,4′-bpy ligands in general positions and two halves of two centrosymmetric 4,4′-bpy ligands, two ClO4 − anions and water molecule with a site-occupancy factor of 0.480 (17). The CuI atoms are in a distorted tetrahedral coordination environment and are bridged by 4,4′-bpy ligands, forming a diamondoid cationic polymeric framework that encloses two symmetry-independent channels along [100], which accommodate perchlorate anions and water molecules.
Highlights
4,40 -bipyridine (4,40 -bpy) under hydrothermal conditions, features a fourfold-interpenetrated diamondoid coordination framework
The asymmetric unit consists of two CuI atoms, three 4,40 -bpy ligands in general positions and two halves of two centrosymmetric 4,40 -bpy ligands, two ClO4 anions and water molecule with a site-occupancy factor of 0.480 (17)
CuI atoms are in a distorted tetrahedral coordination environment and are bridged by 4,40 -bpy ligands, forming a diamondoid cationic polymeric framework that encloses two symmetry-independent channels along [100], which accommodate perchlorate anions and water molecules
Summary
Therapeutics and Diagnostics (Theranostics), School of Pharmacy, Tianjin Medical. University, Tianjin 300070, People’s Republic of China, bClinical Medical College of Tianjin Medical University, Tianjin Medical University, Tianjin 300070, People’s. Republic of China, and cDepartment of Pharmacy, The Second Affiliated Hospital of Tianjin Medical University, Tianjin 300211, People’s Republic of China
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