Abstract
The polarographic reduction at a dropping mercury electrode of several CuII, NiII and CoIII complexes of tetraaza macrocycles has been studied in 0.1M NaClO4 as supporting electrolyte. The CuII complexes show values of half-wave potentials which can be correlated to the ring size and ligand field stabilisation. A similar, though less marked, trend is noticeable in the reduction of the NiII complexes. No such conclusions can be drawn in the case of the CoIII complexes.
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