Abstract
The title compound, [Nd(C8H6NO4)(C2O4)(H2O)]n, is a layer-like coordination polymer. The NdIII ion is coordinated by four carboxylate O atoms from three bridging 5-azaniumylisophthalate (Haip) ligands, four carboxylate O atoms from two oxalate (ox) anions and one ligated water molecule in a tricapped trigonal–prismatic geometry. The Haip anion acts as a μ3-bridge, connecting three NdIII ions through two carboxylate groups; the ox anion adopts a bis-bidentate-bridging mode, linking two NdIII ions. The layer framework is further extended to a three-dimensional supramolecular structure through N—H⋯O and O—H⋯O hydrogen bonds.
Highlights
The title compound, [Nd(C8H6NO4)(C2O4)(H2O)]n, is a layerlike coordination polymer
The NdIII ion is coordinated by four carboxylate O atoms from three bridging 5-azaniumylisophthalate (Haip) ligands, four carboxylate O atoms from two oxalate anions and one ligated water molecule in a tricapped trigonal–prismatic geometry
The layer framework is further extended to a three-dimensional supramolecular structure through N—H O and O—H O hydrogen bonds
Summary
R factor = 0.024; wR factor = 0.056; data-to-parameter ratio = 11.0. The title compound, [Nd(C8H6NO4)(C2O4)(H2O)]n, is a layerlike coordination polymer. The NdIII ion is coordinated by four carboxylate O atoms from three bridging 5-azaniumylisophthalate (Haip) ligands, four carboxylate O atoms from two oxalate (ox) anions and one ligated water molecule in a tricapped trigonal–prismatic geometry. The Haip anion acts as a 3-bridge, connecting three NdIII ions through two carboxylate groups; the ox anion adopts a bis-bidentatebridging mode, linking two NdIII ions. The layer framework is further extended to a three-dimensional supramolecular structure through N—H O and O—H O hydrogen bonds
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have