Abstract

The chapter discusses the formation of discrete polyanions of group 14 and group 15 elements in solid state structures of alkali and alkaline earth metal compounds depending on the degree of reduction and the cation radii. Applying this concept reveals areas of stability of polyanions of different nature. The mapping of the compounds in one diagram presents a comprehensive overview for the regions of existence of the polyanions in the discussed materials. Additionally, solvate structures are summarized, which provide a promising possibility to adjoin new polyanionic arrangements.

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