Abstract

Polyaniline (PANI) nanofibers were fabricated via rapid initiated polymerization in a binary oxidant system consisting of ammonium peroxydisulfate (APS) and hydrogen peroxide (H2O2). The influence of the ratios of APS to H2O2 on the morphologies and optical properties of PANI nanofibers were discussed. It is found that the minimum optical band gap of PANI nanofibers with a relatively uniform diameter of 40 nm can be obtained for the ratio of 1:3.

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