Abstract
ABSTRACTPolyaniline (PANI) is an important conductive polymer because of its wide potential. In this article, we present a modified chemical polymerization method, which employs poly(vinyl alcohol) (PVA) as a doping assistant, for the synthesis of PANI. In this study, the introduced PVA contributed both to the conductivity and specific capacitance. The conductivity markedly increased more than two orders of magnitude from 5.2 to 1052 S/m after a small amount of PVA was introduced. A combination of the amphoteric polymer and acid together as the dopant extended the doping method for the synthesis of conductive PANI. The specific capacitance of PANI occurred up to 382.9 F/g at a current density of 0.5 A/g. The PANIs exhibited fast redox reactions, good ion response, and a short diffusion path of electronic transport. By feat of the hydrophilicity of PVA, the as‐prepared PANI showed a good dispersibility in aqueous solution; this is important for its potential applications. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 42989.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.