Abstract
AbstractPreparation, some properties and applications of the bioanalogous poly(alkylene phosphates), obtained according to the methods elaborated in these authors' laboratory, are reviewed. Ring‐opening polymerization, polyaddition, and two‐step polycondensation methods are effective in the synthesis of polymers with various moieties of nucleic and teichoic acids (NA and TA, respectively). The major aim of the work is to find relatively simple methods allowing high molecular weight polymers to be prepared. Thus, preparation of poly(glycerol phosphate) and poly(trimethylene phosphate) bearing NA bases and related polymers with M¯n ⩾ 104 are described.
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