Abstract

Poly(acrylamide) is grafted onto cross-linked poly (4-vinyl pyridine) (P4-VP) resin “Reillex 425”. Its quaternization with potassium chloroacetate results in cross-linked poly (4-vinyl pyridine) having carboxymethyl pyridinium groups. This resin is grafted with acrylamide after redox initiation through the carboxyl groups with cerium ammonium nitrate. The resulting resin with 111.7 wt% of poly(acrylamide) grafts is a high capacity (3.36 mmol g −1) mercury specific sorbent. Experiments performed under identical conditions with some other ions such as Zn(II), Pb(II), Fe(III) and Cd(II) showed that those metal ions are not sorbed by the resin. Flexible graft chains of poly(acrylamide) provide nearly homogeneous reaction conditions in mercury uptake. Regeneration of the mercury loaded polymer can be achieved by acetic acid treatment.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.