Abstract
In the polymeric title complex, [Zn(C9H7NO4)]n, the ZnII cation is located on a twofold rotation axis and is coordinated by five 2,6-dimethylpyridine-3,5-dicarboxylate (mpdc) anions in a distorted ZnNO4 trigonal–bipyramidal geometry. The mpdc anion is also located on the twofold rotation axis and bridges five ZnII cations, forming the three-dimensional polymeric complex. Weak C—H⋯π interactions are present in the crystal structure.
Highlights
In the polymeric title complex, [Zn(C9H7NO4)]n, the ZnII cation is located on a twofold rotation axis and is coordinated by five 2,6-dimethylpyridine-3,5-dicarboxylate anions in a distorted ZnNO4 trigonal–bipyramidal geometry
The mpdc anion is located on the twofold rotation axis and bridges five ZnII cations, forming the three-dimensional polymeric complex
Weak C—H interactions are present in the crystal structure
Summary
Min = 0.59 e Å3 a College of Chemistry, Chongqing Normal University, Chongqing 400047, People’s. Republic of China, and bCollege of Life Science, Chongqing Normal University, Chongqing 400047, People’s Republic of China. Symmetry codes: (i) x; y; z 12; (ii) x þ 12; y þ 12; z þ 1. R factor = 0.023; wR factor = 0.067; data-to-parameter ratio = 10.3. In the polymeric title complex, [Zn(C9H7NO4)]n, the ZnII cation is located on a twofold rotation axis and is coordinated by five 2,6-dimethylpyridine-3,5-dicarboxylate (mpdc) anions in a distorted ZnNO4 trigonal–bipyramidal geometry. The mpdc anion is located on the twofold rotation axis and bridges five ZnII cations, forming the three-dimensional polymeric complex. Weak C—H interactions are present in the crystal structure
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