Abstract
The title compound, [Nd(OH)(SO4)]n, was obtained hydrothermally from an aqueous solution of neodymium nitrate, 1,2-propanediamine and sulfuric acid. The structure features nonacoordinated neodymium with sulfate and hydroxide anions acting as bridging ligands. The OH group forms a weak O—H⋯O hydrogen bond with an O⋯O distance of 3.224 (5) Å.
Highlights
The title compound, [Nd(OH)(SO4)]n, was obtained hydrothermally from an aqueous solution of neodymium nitrate, 1,2-propanediamine and sulfuric acid
The structure features nonacoordinated neodymium with sulfate and hydroxide anions acting as bridging ligands
H atoms treated by a mixture of independent and constrained refinement Ámax = 0.56 e A À3 Ámin = À2.27 e A À3
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (Nd–O) = 0.004 A; R factor = 0.023; wR factor = 0.057; data-to-parameter ratio = 10.1. The title compound, [Nd(OH)(SO4)]n, was obtained hydrothermally from an aqueous solution of neodymium nitrate, 1,2-propanediamine and sulfuric acid. The structure features nonacoordinated neodymium with sulfate and hydroxide anions acting as bridging ligands. The OH group forms a weak O—HÁ Á ÁO hydrogen bond with an OÁ Á ÁO distance of 3.224 (5) A
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