Abstract
The sandwich structures have been obtained by deposition of organic thin films on commercial tin oxide. Then the organic films were covered by a thin aluminium film. All the films were deposited by evaporation. The organic component was either a thin (150nm) poly(N-vinylcarbazole) (PVK) film or a bilayer constituted of a thin PVK layer covered with a 8-hydroxyquinoline, aluminium (Alq3). When PVK is deposited by classical thermal evaporation there is a shortening effect of the chain length, however, the main properties of the vinyl-carbazole molecules are preserved. These films are photoluminescent with blue light emission. The I–V characteristics of the sandwich structures are typical of such organic sample. They exhibit a rectifying behaviour, with a forward polarisation when the SnO2 electrode is positively biased. They also exhibit electroluminescence. When a single PVK film is used, the signal is quite faint. It is improved when an organic bilayer is used. However, simultaneously there is a red shift of the signal.
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