Abstract
The title compound, [Na2Mn(C3H2O4)2(H2O)2]n, obtained by the hydrothermal reaction of MnCl2·4H2O, NaOH and malonic acid, is a three-dimensional polymeric complex bridged by malonate dianions. The MnII atom, which occupies an inversion centre, has distorted octahedral coordination, with Mn—O bonds in the range 2.1168 (10)–2.2666 (10) Å. The NaI atom has slightly distorted octahedral coordination, with Na—O distances ranging from 2.3700 (14) to 2.6117 (12) Å.
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