Abstract

In the title compound, [CuNa2(C9H4O6)2(H2O)4] n , the CuII cations are square-planar coordinated by carboxylate O-atom donors from four different hydrogen benzene-1,2,4-tricarboxylate (btcH) ligands, thereby forming [Cu(btcH)2] n 2n− coordination polymer ribbons. These are connected by octahedrally coordinated and hydrated NaI cations within Na2(μ-H2O)2 clusters to construct the full [Na2(H2O)4Cu(btcH)2] n three-dimensional coordination polymer.

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