Abstract
In the title complex, [CdCl2(C4H8O2)]n, two different CdII ions are present, one in a general position and one with site symmetry 2. The CdII ions are coordinated by two O atoms from two 1,4-dioxane ligands and four chloride anions in a slightly distorted octahedral geometry and is connected to neighboring CdII ions by two bridging chloride anions, generating infinite linear chains along the a axis. These chains are further interconnected by bridging 1,4-dioxane ligands, affording a three-dimensional network.
Highlights
The CdII ions are coordinated by two O atoms from two 1,4-dioxane ligands and four chloride anions in a slightly distorted octahedral geometry and is connected to neighboring CdII ions by two bridging chloride anions, generating infinite linear chains along the a axis
These chains are further interconnected by bridging 1,4-dioxane ligands, affording a three-dimensional network
Symmetry codes: (i) −x+1/2, −y+1/2, −z+1; (ii) −x+1, y, −z+1/2; (iii) −x+1/2, y+1/2, −z+1/2; (iv) −x+1, −y, −z+1; (v) −x+1/2, y−1/2, −z+1/2
Summary
R factor = 0.019; wR factor = 0.105; data-to-parameter ratio = 19.0. In the title complex, [CdCl2(C4H8O2)]n, two different CdII ions are present, one in a general position and one with site symmetry 2. The CdII ions are coordinated by two O atoms from two 1,4-dioxane ligands and four chloride anions in a slightly distorted octahedral geometry and is connected to neighboring CdII ions by two bridging chloride anions, generating infinite linear chains along the a axis. These chains are further interconnected by bridging 1,4-dioxane ligands, affording a three-dimensional network
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