Abstract
The title compound, {(C2H8N)2[Zn2(C8H4O4)3(C2H7N)2]·2C3H7NO·6H2O}n, consists of two-dimensional non-interpenetrated sheets with 63 topology, which are stacked together in an …ABAB… packing mode along the c axis. The distance between adjacent A and B sheets is ca 7.3 Å. In the structure, the ZnII center is coordinated by three O atoms from three terephthalate groups and one N atom from one dimethylamine ligand, adopting a distorted tetrahedral geometry. All solvent water molecules are disordered. In the structure, N—H⋯O and O—H⋯O hydrogen bonds are observed.
Highlights
The ZnII center is coordinated by three O atoms from three terephthalate groups and one N atom from one dimethylamine ligand, adopting a distorted tetrahedral geometry
The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry
An approximate treatment of cell esds is used for estimating esds involving l.s. planes
Summary
Key indicators: single-crystal X-ray study; T = 291 K; mean (C–C) = 0.004 Å; disorder in solvent or counterion; R factor = 0.049; wR factor = 0.106; data-toparameter ratio = 18.1. The title compound, {(C2H8N)2[Zn2(C8H4O4)3(C2H7N)2]2C3H7NO6H2O}n, consists of two-dimensional non-interpenetrated sheets with 63 topology, which are stacked together in an . The distance between adjacent A and B sheets is ca 7.3 Å. The ZnII center is coordinated by three O atoms from three terephthalate groups and one N atom from one dimethylamine ligand, adopting a distorted tetrahedral geometry. N—H O and O—H O hydrogen bonds are observed
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