Abstract

In the title compound, {[Mn(C6H2D2NO2)2(H2O)]·C2H6O}n, the MnII metal centre displays a slightly distorted octa­hedral coordination geometry, provided by three O and two N atoms of five isonicotinate ligands and one O atom of a water mol­ecule. There are two types of isonicotinate anions, one acting as a bridging tridentate group and the other in a bridging bidentate fashion, to form a polymeric three-dimensional network. The structure is stabilized by intra- and inter­molecular O—H⋯O and C—H⋯O hydrogen-bond inter­actions.

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