Poly acrylic acid stabilized magnetic nanoemulsions for visual defect detection: Effect of pH on detection sensitivity and colloidal stability

Abstract

Magnetic field assisted tunable colour contrast in magnetic nanoemulsions is exploited for visual detection of defects in ferromagnetic components. We demonstrate an enhanced defect detection sensitivity by stabilizing oil-in-water magnetic nanoemulsion with poly acrylic acid (PAA) at varying pH. In this detection technique, the variation of magnetic permeability, in the vicinity of the defects, causes magnetic flux leakage, which results in a distinct colour contrast on the magnetic nanoemulsion sensor due to the formation of anisotropic periodic structures, parallel to the external field direction, where the inter-droplet spacing within the linear chains depends on the effective magnetic flux. By exploiting this colour and magnetic flux dependence, severity of the defects is assessed by observing the colour contrast. Our studies indicate that defect detection sensitivity decreases with increasing pH due to globule-to-coil conformational transition of the interfacial PAA molecules. With increasing pH, the PAA network swells due to mobile counter-ions induced osmotic pressure and electrostatic repulsion between the charged monomer units, leading to a solvated coil-like configuration, which is confirmed from the increase in hydrodynamic diameter and zeta potential. The inter-droplet force measurements show an increase in decay length by ~3.5 times, when pH is increased from ~1.5 to ~4.0. The lower decay length at pH ~ 1.5 indicates the formation of linear chain-like structures with smaller inter-droplet spacing near the defect edges, where the magnetic flux leakage is maximum. This results in a fewer number of randomly oriented droplets at the defect centre, thereby enhancing the defect detection sensitivity at lower pH. However, nanoemulsions stabilized at pH > 3 show increased colloidal stability, as compared to pH ~ 1.5. Our studies indicate that nanoemulsions at pH ~ 3.5 exhibit an optimum colloidal stability with good defect detection sensitivity. The obtained results are beneficial for developing high sensitivity, reliable and reusable magnetic nanoemulsion sensors for naked eye visualization of defects in ferromagnetic components.