Abstract
The asymmetric unit of the title compound, [Rb(C6H3N2O5)(H2O)]n, comprises a rubidium cation, a 2,4-dinitrophenoxide anion and a water molecule. The Rb+ cation is 11-coordinated by O atoms from 2,4-dinitrophenolate anions and water molecules. The metal centre is firstly coordinated by two μ3-H2O to form a one-dimensional ladder-shaped unit, [Rb2(μ3-H2O)2], which is further linked by 2,4-dinitrophenolate to give the three-dimensional framework of the title compound. The crystal structure involves O—H⋯O hydrogen bonds.
Highlights
[Rb(C6H3N2O5)(H2O)]n, comprises a rubidium cation, a 2,4dinitrophenoxide anion and a water molecule
The metal centre is firstly coordinated by two 3-H2O to form a one-dimensional ladder-shaped unit, [Rb2(3-H2O)2], which is further linked by 2,4-dinitrophenolate to give the three-dimensional framework of the title compound
Symmetry codes: (v) −x, −y+2, −z; (ix) −x+1, y+1/2, −z+1/2
Summary
R factor = 0.037; wR factor = 0.101; data-to-parameter ratio = 11.2. H atoms treated by a mixture of independent and constrained refinement max = 0.50 e Å3. Symmetry codes: (i) x; y þ 2; z; (ii) x þ 1; y þ 12; z þ 12. [Rb(C6H3N2O5)(H2O)]n, comprises a rubidium cation, a 2,4dinitrophenoxide anion and a water molecule. The Rb+ cation is 11-coordinated by O atoms from 2,4-dinitrophenolate anions and water molecules. The metal centre is firstly coordinated by two 3-H2O to form a one-dimensional ladder-shaped unit, [Rb2(3-H2O)2], which is further linked by 2,4-dinitrophenolate to give the three-dimensional framework of the title compound.
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