Abstract
The title compound, [Na(C12H8N2O8P)], consists of one Na+ cation and one bis(p-nitrophenyl)phosphate anion with a considerable distortion of the phosphate tetrahedron due to the presence of two P—O ester bonds. The anion bridges five Na+ cations whereby each cation is chelated by the nitro O atoms of one anion and bonded via a nitro O atom and phosphate O atoms to four other anions. This bridging arrangement leads to the formation of double layers parallel to (001). Adjacent layers are linked through weak C—H⋯O hydrogen bonds.
Highlights
Cation and one bis(p-nitrophenyl)phosphate anion with a considerable distortion of the phosphate tetrahedron due to the presence of two P—O ester bonds
Atoms of one anion and bonded via a nitro O atom and phosphate O atoms to four other anions. This bridging arrangement leads to the formation of double layers parallel to (001)
Adjacent layers are linked through weak C—H O
Summary
University of Wroclaw, Faculty of Chemistry, 14 Joliot-Curie St, 50-383 Wroclaw, Poland. R factor = 0.030; wR factor = 0.090; data-to-parameter ratio = 31.1. Cation and one bis(p-nitrophenyl)phosphate anion with a considerable distortion of the phosphate tetrahedron due to the presence of two P—O ester bonds. Na+ cations whereby each cation is chelated by the nitro O atoms of one anion and bonded via a nitro O atom and phosphate O atoms to four other anions. This bridging arrangement leads to the formation of double layers parallel to (001). Adjacent layers are linked through weak C—H O hydrogen bonds.
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
