Abstract
The title compound, [Zn(C6H4NO3)(N3)], has been prepared by the reaction of nicotinate N-oxide acid, zinc(II) nitrate and sodium azide. The Zn atom is five coordinated by two azide anions and three nicotinate N-oxide ligands. Each nicotinate N-oxide bridges three Zn atoms, whereas the azide bridges two Zn atoms, resulting in the formation of a two-dimensional metal–organic polymer developing parallel to (100).
Highlights
The title compound, [Zn(C6H4NO3)(N3)], has been prepared by the reaction of nicotinate N-oxide acid, zinc(II) nitrate and sodium azide
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: DN2407)
The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.008 A; R factor = 0.065; wR factor = 0.122; data-to-parameter ratio = 13.9. The title compound, [Zn(C6H4NO3)(N3)], has been prepared by the reaction of nicotinate N-oxide acid, zinc(II) nitrate and sodium azide. The Zn atom is five coordinated by two azide anions and three nicotinate N-oxide ligands. Each nicotinate N-oxide bridges three Zn atoms, whereas the azide bridges two Zn atoms, resulting in the formation of a two-dimensional metal–organic polymer developing parallel to (100). Related literature For background to metal–azide complexes, see: Escuer et al (1997); Liu et al (2005); Monfort et al (2000); Shen et al (2000). Crystal data [Zn(C6H4NO3)(N3)] Mr = 245.50 Monoclinic, P21=c a = 8.1132 (16) Ab = 6.1342 (12) Ac = 15.786 (3) A = 101.19 (3)
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