Pollution Status of Dumpsites within Uyo Metropolis, Akwa Ibom State, Nigeria

Abstract

The study evaluates the heavy metals, geo-accumulation index and contamination factor in soil around dumpsites in Uyo, Akwa Ibom State, Nigeria. Soil samples were collected, during rainy season, at depth of 0-15cm and 15-30cm from two study sites (A, B) and a control site (C). Soil samples were all analyzed for heavy metals (Pb, Ni, Cd and Cu) using Atomic Absorption Spectroscopy (AAS). The concentration of Lead at site A for depth 0-15 cm ranged from 13.71 -14.90 mg/kg with a mean value of 14.38 ± 0.61 mg/kg; Nickel varied from 2.35 – 3.22 mg/kg (2.74 ± 0.44 mg/kg); Cadmium ranged from 3.78 – 4.13 mg/kg (3.93 ± 1.18 mg/kg); Copper ranged from 27.84 – 28.34 mg/kg (28.14 ± 0.27 mg/kg). The heavy metals concentration in soil at sites A and B followed the sequence, Cu > Pb > Cd > Ni while at the control site; Cu > Cd > Ni > Pb. The calculated geo-accumulation index (Igeo) showed that the soil samples from sites A and B for Pb, Ni and Cu belong to class 2, which implies that the soil was moderately contaminated. The Igeo values for Cd at sites A and B were classified as 4, indicating a strongly contaminated soil. However, Igeo of Cd at the control site is class 3, implying moderately to strongly contaminated soil. Calculated contamination factor (CF) showed that Pb, Ni and Cu for sites A, B and control at depths 0-15cm were in class 1 (low contamination), while Cd contamination was class 4 except at control site (15 -30cm) which showed CF of class 3. The contamination degrees (CD) for the sampling sites A and B showed considerable contamination and their pollution load index (PLI) indicated a progressive deterioration of the sites; however, the control site recorded very minimal state of pollution. Generally, the results found that the top soil (0 – 15 cm) was more contaminated than the sub soil (15 – 30 cm) of all sample sites studied. The results of this study imply that the inhabitants around Sites A and B are exposed to Cadmium pollution and the soil is not suitable for agricultural practice, since plants can take up these toxic metals and bio-accumulate them in their tissues. Cadmium, at high concentration in plants, can cause serious clinical and physiological effects on humans when consumed as food.