Abstract
In order to assess the pollution levels and health risks of PM2.5-bound metals in Baoding City before and after the heating period, samples were collected in 2016 at Hebei University from September 25th to November 14th during the non-heating period, and November 15th to December 26th during the heating period, respectively. ICP-MS was applied to analyze seven heavy metals (Cr, Zn, Cu, Pb, Ni, Cd and Fe). The statistical analysis, enrichment factor (EF), pollution load index method, and Risk Assessment Method proposed by U.S. EPA were used to evaluate the non-carcinogenic risks of six of these heavy metals (Cr, Zn, Cu, Pb, Ni and Cd) and carcinogenic risks of three of these heavy metals (Cr, Ni and Cd). The results showed three main results. First, the average daily PM2.5 concentrations of the national air monitoring stations was 155.66 μg·m−3 which was 2.08 times as high as that of the second level criterion in China (75 μg·m−3) during the observation period. Compared with the non-heating period, all heavy metals concentrations increased during heating period. The growth rates of Pb and Ni were the highest and the lowest, which were 88.03 and 5.11 percent, respectively. Second, the results of enrichment factor indicated that the EF values of all heavy metals were higher during the heating period in comparison with during the non-heating period, but the degree of enrichment of all heavy metals remained unchanged. Not only those, Cr and Ni were minimally enriched and were affected by both human and natural factors, Pb, Cu and Zn were significantly enriched and were mainly affected by human factors, the enrichment of Cd was much higher than that of the other heavy metals, exhibiting extremely high enrichment, mainly due to human factors during the whole sampling period. The results of the pollution load index indicated that the proportions of the number of highly and very highly polluted PM2.5-bound metals were the highest during the heating period, while the proportion of moderately polluted PM2.5-bound metals was the highest during the non-heating period. The combined pollution degree of heavy metals was more serious during the heating period. Third, according to the health risk assessment model, we concluded that the non-carcinogenic and carcinogenic risks caused by inhalation exposure were the highest and by dermal exposure were the lowest for all kinds of people. The overall non-carcinogenic risk of heavy metals via inhalation and subsequent ingestion exposure caused significant harm to children during the non-heating and the heating periods, and the risk values were 2.64, 4.47, 1.20 and 1.47, respectively. Pb and Cr exhibited the biggest contributions to the non-carcinogenic risk. All the above non-carcinogenic risks exceeded the standard limits suggested by EPA (HI or HQ < 1). The carcinogenic risk via inhalation exposure to children, adult men and women were 2.10 × 10−4, 1.80 × 10−4, and 1.03 × 10−4 during the non-heating period, respectively, and 2.52 × 10−4, 2.16 × 10−4 and 1.23 × 10−4 during the heating period, respectively. All the above carcinogenic risks exceeded the threshold ranges (10−6~10−4), and Cr posed a carcinogenic risk to all people.
Highlights
In recent years, with economic development and industrial expansion, long-term and persistent air pollution incidents have come to occur frequently, and complex regional atmospheric pollution problems have become increasingly significant [1,2,3]
The carcinogenic risks posed by three heavy metals (Cd, Cr and Ni) and the non-carcinogenic risks posed by six heavy metals (Cr, Pb, Ni, Cd, Cu and Zn) to the public were analyzed in this study
The enrichment factor (EF) values of Cr and Ni belonged to Grade 2, indicating that Cr and Ni were mildly enriched and affected by natural sources and human sources together
Summary
With economic development and industrial expansion, long-term and persistent air pollution incidents have come to occur frequently, and complex regional atmospheric pollution problems have become increasingly significant [1,2,3]. The surface of this particulate fraction could be used as the carrier of viruses, bacteria and heavy metals. Some of these particles will enter the body through the respiratory system, increasing morbidity and mortality due to cardiovascular diseases [9,10]. A recent Italian study shows that living in towns at various levels of air pollution during childhood will play an important role in the development of chronic diseases in adulthood, including cancer [11]. Heavy metals associated with the PM2.5 fraction may enter the human body through dermal, inhalation, and ingestion pathways [16,17].
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