Pollution characteristics of phthalate acid esters in agricultural soil of Yinchuan, northwest China, and health risk assessment.

Abstract

Eighty-nine agricultural surface soil samples from different types of land of Yinchuan were collected and detected for sixteen phthalate acid ester (PAE) compounds; the pollution characteristics and pollution distribution were analyzed. In addition, the potential health risk exposures to local resident of six priority control phthalates by the US EPA were assessed. All soil samples were contaminated with PAEs, the total concentrations of Σ16PAEs were between 0.391 and 11.924mgkg-1, and the mean concentrations were 4.427mgkg-1 in soil. Among the sixteen PAE congeners, DMP was the most abundant component, which accounted for average 44.64% of the total PAEs, then DnBP and DEHP, which accounted for the average contribution rate, were 21.25% and 23.34%, respectively, and DpHP was not detected in all soil samples. Risk assessment indicated that the risk of non-carcinogenesis in this study was within the acceptable range; however, the carcinogenic risk of DEHP through intake dietary significantly exceeded the carcinogenic level recommended by the US EPA (1 × 10-6) and therefore presented a potential carcinogenic risk. More considerable attention should be given to the PAEs contamination status in soils and potential effects on local resident health.