Abstract
Polarographic studies of tetravalent titanium in salicylate and sulphosalicylate media revealed the successive appearance of different titanium-salicylate or titanium-sulphosalicylate complexes. The complexes are derived from each other by a process of hydrolysis. Two salicylate complexes were detected and three sulphosalicylate complexes. In the presence of excess complexing agent and in the pH range of 1–9 the equilibrium of the different species could be represented as follows: ▪ A mechanism is proposed which accounts for the different polarographic waves.
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