Abstract

The polarographic study of uranyl(IV)-halides complexes in DMS0 showed the formation of [UO2-F2] and [UO 2Cl] + stable species, while bromide and iodide ions do not form stable uranium(VI) complexes, in agreement with the “hard” character of uranyl ( VI) ion. The complexes formation between pseudohalides and uranium(VI) evidentiated the following species, stable enough to be polarographically revealed: [UO 2N 3 3] −, [UO 2CN) 2] and [UO 2(CN) 2]; on the contrary thiocyanate ion does not form sufficiently stable complex species in DMSO. Cyclic voltammetric tests were also performed to investtgate the anodic dissolution process of mercury in the presence of azide ion.

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