Abstract
The wave obtained in the a.c. polarography of chloride is attributed mainly to the adsorption of chloride ion which results in a high differential capacity of the electrical double-layer. The alternating current at potentials more negative than the summit of this a.c. wave is non-faradaic in character since no faradaic direct current can be detected in this potential region. D.c. polarographic current-time curves indicate that discharge of chloride ion begins almost discontinuously at a potential corresponding to the summit of the a.c. wave.
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