Polarization in elastic scattering: close-coupling studies on ArN 2

Abstract

We present the results of close-coupling calculations of m j -dependent differential and integral cross sections for j 1 = 2 → j 2 = 2 rotationally elastic ArN 2 collisions. Two potential surfaces were used with differing long-and short-range anisotropies. If the anisotropy is long-ranged the scattering of an isotropic beam results in a significant angle dependent polarization of the elastically scattered products. To a certain extent this reflects a selective loss of m j -state population due to rotationally inelastic transitions. For quantization along the initial relative velocity vector or perpendicular to the scattering plane, the depolarization of an initially m j -state selected beam vanishes in the forward direction and is significantly less than the statistical limit at all angles, which indicates a dynamical conservation of the direction of the molecular rotational angular momentum. By contrast, in the helicity frame depolarization is much more pronounced. The oscillatory structure present in the rotationally inelastic differential cross section does not appear to be quenched by the interference between various m → m′ transitions.