Abstract

Polarization behavior of the Ni‐200 electrode in at 1000°C under at 1 atm is linear over an overpotential range of and is consistent with resistance polarization in the electrolyte. Similar polarization behavior of the 304 stainless steel electrode and of the Ni‐200 electrode in suggests that the charge transfer mechanism is a sulfide/polysulfide exchange reaction. Nonelectrodic dissolution of nickel in the melt occurs at , apparently due to oxidation by . Anomalously high dissolution rates are attributed to trace polysulfide.

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